EPJ B - sp3 domains in graphite induced by visible light

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Published on 03 May 2010

Keiichiro Nasu reviews models of photo-induced structural phase transitions in relation to recent experimental results on unconventionally photoactive solids, where the relaxation of optical states results in macroscopic excited domains with new structural and electronic orders. Two key concepts, the hidden multi-stability of the ground state and proliferations of optically excited states are discussed. Taking the ionic to neutral phase transition in an organic charge-transfer crystal as example, the author documents the fundamental nature of photo-induced structural phase transitions. Further, Nasu recounts the details of the discovery of a new photo-induced phase of carbon, named "diaphite", located in between graphite and diamond. The mechanism of this photo-induced structural phase transition is discussed in terms of the proliferation of photo-generated inter-layer charge-transfer excitations in the visible regime.